December 1963 Electronics World
Table of Contents
Wax nostalgic about and learn from the history of early electronics. See articles
Electronics World, published May 1959
- December 1971. All copyrights hereby acknowledged.
Decades from now, readers will look back at
today's science magazines reporting on topics such as breakthroughs on quantum computing and quantum
entanglement the way we now look back at articles from the middle to latter half of the last century,
and be amazed at how the understanding and exploitation of various technologies was just getting started.
This particular piece on quantum device is not at all related to the two aforementioned topics; rather,
it introduces the concept of discrete (quantum) energy levels of atomic electronic orbitals and how
they determine photon absorption and emission. It is a good introduction to or refresher of the phenomenon
that relates photon energy to its wavelength via Planck's constant.
Quantum Devices / how they work
By John R. Collins
When certain molecules are excited by electromagnetic radiations,
they change energy levels. When they drop back to their previous levels, they give up energy. This is
basis for masers, lasers, atomic clocks.
Several striking developments in the past few years have advanced electronics in a sort of quantum
jump - to use an expression that is becoming commonplace. It is especially appropriate here because
many new devices are outgrowths of the quantum theory, which, although more than half a century old,
is just beginning to be exploited.
The most familiar of the new quantum devices are the maser and laser, which embody entirely new principles
of amplification for microwaves and light rays. In addition, there are molecular and atomic clocks with
accuracies better than 1 second in 40 years, the tunnel diode which can amplify or oscillate in the
gigacycle region, and certain spectrometers capable of making detailed chemical analysis of compounds
by electronic means.
Much of the quantum theory is hard to visualize or to represent with mechanical models. Electronics
has come a long way since water tanks represented voltage, narrow pipes portrayed resistors, and walking
on a garden hose illustrated modulation of d.c. with a.c. Moreover, the quantum theory is not a single
rule like Ohm's Law, but an accumulation of information about the atom that fills many volumes. While
the theory is definitely an area for specialists, its impact on modern electronics has been so great
that no technician who wants to understand the newest equipment can afford to remain ignorant of this
Fig. 1 - Among the three energy levels in a molecule, the energy difference between
each level is related to characteristic frequency. For example, f23 is the frequency corresponding
to energy difference between levels 3 and 2.
Conventional electron devices, such as electron tubes, function by means of the effect of an electrostatic
field on the movement of charged particles, usually electrons. Quantum devices, however, utilize changes
that take place inside particles owing to the effect of an electromagnetic field on their internal structure.
The particles may be either molecules, atoms, or ions. In the following discussion, the term molecule
is used to denote any of the three kinds of particles.
Molecules are made up of electrons and atomic nuclei which, according to the quantum theory, can
assume only certain fixed motions and orientations. Each set of motions or orientations is associated
with a discrete amount of internal energy called the "energy level" (Fig. 1). At any given instant,
a molecule may be at anyone of a number of possible energy levels. It cannot exist anywhere in between.
The fact that it jumps from one level to another is the origin of the so-called quantum jump. When a
molecule jumps from a lower to a higher energy level, it absorbs energy and is said to become excited.
When it drops to a lower level, it gives up energy.
A natural question is, "What takes place inside the molecule when energy is absorbed or emitted?"
There is no simple answer to explain all changes in energy levels. In some instances, the absorption
of energy is accompanied by the transition of an electron from its usual orbit to a new orbit more remote
from the nucleus. An equal amount of energy is emitted when the electron returns to its original orbit.
A second type of transition involves atoms having unpaired electrons. Each individual electron may
be viewed as a small, spinning magnet with a north and south pole. In most substances, electrons are
paired off with their poles opposite to each other, so that their magnetic fields are cancelled. In
a few substances, however, cancellation is incomplete, leaving an unpaired electron in each atom.
When such substances are placed in a magnetic field, the unpaired electrons can have just one of
two positions-a lower energy state in which the electron's north pole points in the direction of the
magnetic field, or a higher energy state in which its south pole is in the direction of the field. The
frequency at which energy is absorbed or emitted in this kind of transition is directly proportional
to the strength of the external magnetic field.
In a third case, energy transitions may be accompanied by changes in the relative positions of elements
making up a molecule. The ammonia molecule (NH3), for example, is shaped like a pyramid,
with an atom of nitrogen at the apex and a hydrogen atom at each of the three corners of the base. When
excited, the nitrogen atom apparently drops through the base to the other side, inverting the pyramid.
Regardless of the reasons, however, the important point is that molecules will absorb and emit energy
in fixed amounts, and the transition from one level to another is not smooth, but takes on the appearance
of a jump.
Fig. 2 - Rules for the interaction of molecules with photons.
Although the absorption and emission of energy by various substances had been observed for some time,
it was not until 1900 that Max Planck made the important discovery that a fixed relationship exists
between the energy and the frequency of the radiation. At the time Planck was studying radiation of
energy from a hot object. He noted that the amount of radiant energy emitted at each wavelength from
the ultraviolet to the infrared could be obtained by multiplying the frequency of the radiation by a
constant amount of h, equal to 4.13 x 10-15 electron-volt-second. His discovery
is expressed by the formula E = hf where E in this case stands for energy, not voltage, and
f is frequency.
Just as Einstein found a way of expressing energy in terms of mass, Planck's formula provides a means
of expressing energy in terms of frequency. Although the theory started with Planck, its further development
was carried out by many of the greatest scientists and physicists of this century, including Einstein,
Pauli, Rutherford, and Heisenberg. It was soon found that Planck's formula applies not only to energy
emitted from a hot object, but to the entire electromagnetic spectrum. It should be noted that Planck's
constant is exceedingly small and therefore the amount of energy involved becomes appreciable only at
the upper end of the spectrum - that is, in the region of microwaves, x-rays, and light.
Since h is a constant, Planck's formula implies that energy E is always absorbed or emitted
in discrete packets or quanta which are called photons. A photon is equal to the product of its characteristic
frequency f and the constant h. Since frequency may vary over a wide range, all photons
are obviously not of equal energy. However, in no case is energy emitted or absorbed in a fraction of
Spontaneous and Stimulated Emission
Under ordinary circumstances, some of the particles in any substance will be at a higher energy level
and some at a lower level at any given time. Particles are raised to a higher level by heat, light,
electron bombardment, etc. They will naturally revert to a lower level after a period of time, and in
doing so spontaneously release photons. These photons may strike other molecules and cause them to jump
to a higher level in turn.
Fig. 1 shows, in diagram form, the energy levels that might be found in a molecule. Each transition
from one level to another would be accompanied by absorption or emission of radiant energy of a characteristic
frequency. If f23 represents the frequency of the radiation absorbed or emitted
in a transition between levels 2 and 3, we can determine the energy E23 involved from the
relation: E23 = hf23. Similarly, if we know the energy of the photons
emitted, we can find the frequency by rearranging Planck's formula to: f23 = E23/h.
The time required for a molecule in a higher state to revert spontaneously to a lower state depends
on the kind of molecule and the type of transition involved. The probability of a transition taking
place may be greatly increased or stimulated by the presence of radiation of the required characteristic
frequency. The greater the density of this radiation, the greater the probability that a transition
Fig. 2 shows how molecules react with electromagnetic radiation of the characteristic frequency.
It is important to note that a photon of the correct frequency (or energy) striking a molecule at the
lower energy level will cause it to jump to a higher level. However, if a photon of the same energy
strikes a molecule already in the higher energy state, the molecule will revert to the lower state and
two photons will be emitted. It is this characteristic that makes possible the amplification of microwaves
and light by masers and by both solid-state and gas lasers.
The Ammonia Clock
Fig. 3 - Excited ammonia molecules are separated from unexcited molecules to form
the basis of an ammonia frequency standard.
One of the first practical applications of the above principles was the molecular clock using the
ammonia molecule. This molecule has two energy levels separated by a gap corresponding to 23,870 mc.
Ammonia has the unusual property that at the lower level the molecule is attracted by an electrostatic
field, while at the higher level it is repelled.
Fig. 3 shows how this characteristic is used to separate high-energy molecules from a mixture. Ammonia
gas containing both excited and unexcited molecules is emitted from a source at high pressure and is
passed in a narrow stream through a focuser. The focuser is made up of a system of charged conductors
that provide a strong electrostatic field. The low-energy molecules are attracted by the conductors
and are thus dispersed along the sides of the focuser. The high-energy molecules, however, are repelled
by the conductors and are therefore concentrated in a narrow beam at the very center of the focuser.
They are thus directed into the narrow port of a resonant cavity while the low-energy types are deflected
The dimensions of the cavity are exactly proportioned to make it resonant at precisely 23,870 mc.
This tends to reinforce the oscillations which occur at that frequency as the molecules drop to the
lower energy level, so that a strong signal is generated. This signal is conducted from the cavity by
a waveguide. The flow of energized ammonia molecules into the cavity is regulated at the level necessary
to make up for losses and sustain oscillations. The output is a frequency of 23,870 mc. of the utmost
purity, with no sidebands or noise and serves as a precise frequency or time standard.
Masers and Lasers
Fig. 4 - Distribution of molecules in a 3-energy level maser. (A) shows normal distribution
before pumping where most molecules are in the lowest energy level and fewest in the highest level.
In (B), molecules pumped from level 1 to level 3 fall back to either level 1 or level 2 so that the
total number in level 2 exceeds the number that are present in level 1.
Fig. 5 - When a chromium-doped ruby rod is excited by the intense light from a flashlamp,
it emits a red, coherent light.
It was pointed out previously that if radiation of the proper frequency strikes a molecule in the
excited state, the output will be two photons of the same frequency. Therefore, if enough molecules
are in an excited state when struck by these photons, the result will be the amplification at the characteristic
frequency. The apparatus for accomplishing this is the maser - an acronym standing for microwave amplification
by stimulated emission of radiation.
Solids are usually employed for masers since their molecules are more concentrated than those of
gases. Early masers were two-level devices in which molecules were excited by "pumping" with radiation
corresponding to the transition frequency. Such masers could amplify a signal only during the interval
between pumping and spontaneous relaxation.
This difficulty was solved by the three-level maser (Fig. 4).
Normally, most molecules are at the lowest level, the fewest at the highest level. The pumping frequency
corresponds to the energy difference between levels 1 and 3, so that molecules are transferred from
the lowest to the highest level. During the relaxation period they drop in about equal numbers to levels
2 and 1.
If the pumping radiation is strong enough, more molecules can be kept in level 2 than in level 1,
and the frequency corresponding to the energy difference between levels 1 and 2 can be used for amplification.
Since this frequency is different from the pump frequency, the apparatus can be operated as a continuous
A resonant cavity is used in the case of the ammonia clock, and cryogenic equipment is employed to
reduce noise. Noise level is extremely low, so that masers may be used to amplify very weak signals,
such as those encountered in radio telescopes and long-distance radar.
The laser (light amplification by stimulated emission of radiation) is closely related to the maser
and requires little additional comment. It was recognized that light could be amplified in the same
way as microwaves, provided that the energy difference between two energy levels corresponds to a frequency
in the light region of the spectrum. Because of the short wavelength of light, the problem of devising
a resonant cavity was formidable. This difficulty was overcome, however, by using mirrored surfaces
at the end of the laser crystal.
The test setup is shown in Fig. 5. A ruby crystal, composed of aluminum oxide and containing a small
percent of chromium oxide which causes its red color, is formed in a rod several inches long. One end
is completely silvered to give full reflection, the other with a very thin coating so that some light
will pass through it.
A brilliant flash lamp pumps the chromium atoms to a higher energy level. Laser action begins when
one of the energized atoms spontaneously emits a photon in the direction of one of the mirrored ends.
Emission in other directions passes through the side of the rod and has little effect. However, emission
in the direction of one of the mirrors sets up a chain reaction as photons bounce back and forth between
the mirrored surfaces, striking other energized atoms in the process and causing each to emit two photons.
When amplification is great enough, a narrow beam of extremely intense red light is emitted from
the partially silvered end of the rod. The light is coherent, covering a single frequency, and provides
a striking demonstration of the operation of the quantum theory.
The laser is finding wide use in medical, chemical, and biological research, and may be the principal
means of communications for space vehicles. Lasers may also lead to the design of very-high-resolution
The quantum theory has provided two new kinds of spectrometers, called the nuclear magnetic resonance
(NMR) and the electron paramagnetic resonance (EPR) spectrometer. The first type uses the gyromagnetic
properties of atomic nuclei, the second the orientation of unpaired electrons. Electromagnetic radiation
is provided by a combination of an r.f. signal and a strong magnetic field. The r.f. signal is usually
maintained at a constant level while the magnetic field is usually increased.
Energy is absorbed from the system at resonance points that correspond to energy level transitions.
Since these are different for each kind of atom making up the unknown sample, the composition can be
determined by measuring the density of the magnetic field at the points where absorption occurs. The
degree of energy absorption is related to the number of atoms involved, so both a qualitative and quantitative
analysis is provided.
An r.f. signal of about 10 kc. is usually employed for NMR spectrometers. Since EPR spectrometers
are designed to take advantage of fields associated with unpaired electrons which resonate at much higher
frequencies than atomic nuclei, it is necessary to use microwave plumbing.
The above descriptions cover some of the more important quantum devices. The list is not exhaustive,
as quantum mechanics is influencing much current developmental work. In view of the successes already
attained, there is reason to believe the quantum theory will be a major factor in invention for many
years to come.
Posted December 14, 2016