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July 1964 Popular Electronics
Table of Contents
Wax nostalgic about and learn from the history of early electronics. See articles
from
Popular Electronics,
published October 1954 - April 1985. All copyrights are hereby acknowledged.
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Details of ancient
Parthian electrochemical batteries unearthed near Baghdad by archaeologist
Wilhelm Konig, dating over 2,000 years, was reported in this 1964 Popular
Electronics magazine article. Housed in earthenware jars sealed with
asphaltum (bitumen), they featured a copper cylinder soldered with 60/40
tin-lead alloy - identical to modern electronics, prior to PB-free mandates -
encasing a corroded iron rod for electrodes, enabling electroplating of gold,
silver, and antimony via electrolytes like copper sulphate, ferrocyanides, or
lye. GE engineer Willard F.M. Gray replicated them successfully for Pittsfield's
Berkshire Museum, using iron rods for series connections. More cells surfaced in
a Seleucia magician's hut and Berlin Museum, suggesting secret artisanal use,
possibly traded as gifts to Cleopatra. Lamenting lost ancient knowledge from
conquests, the piece frames these as rediscoveries.
Babylon Battery

Babylonian battery, shown in the cross-sectional view at left,
is similar to today's dry cell.
By Walter G. Salm
Electric batteries over 2000 years ago? Not really impossible, if you stop to
ponder the considerable amount of knowledge the ancients possessed. Unfortunately,
most of this knowledge was lost during various conquests and library burnings.
These early electrochemical batteries were first brought to light by a German
archaeologist, Wilhelm Konig, working for the Iraq Museum. They were discovered
in the ruins of an ancient Parthian town on Khujut Rabu'a, a hill not far from Baghdad.
The cells were apparently used for electroplating gold, and as there were no patent
laws, the processing details were passed from father to son, and kept closely guarded.
Cell Construction
The ancient cells were reported to the American scientific press in 1939 by Willy
Ley, a science historian. He described the central cell elements: a copper cylinder
containing an iron rod that had been corroded as if by chemical action. The cylinder
was soldered with a 60/40 lead-tin alloy, the same solder alloy we use today. The
electrolyte was another matter. As this was thoroughly dried by time, it's anybody's
guess. However, there were a number of usable chemicals around in those days that
could have done the job.

Batteries were built into earthenware jars such as this one.
Asphaltum was used to seal battery element in place.

Cut-away model exposes interior of ancient cell. Vase was not
for looks, but to support elements.
Willard F. M. Gray, an engineer at GE's Pittsfield, Massachusetts, plant constructed
replicas of these cells, and used copper sulphate as an electrolyte. Mr. Gray's
models, shown in the photographs, are now in the Berkshire Museum in Pittsfield.
The earthenware jars used to house the original cells kept the cells upright, and
the tops were sealed with asphaltum, a caulking compound that cannot be duplicated
today. Mr. Gray used black sealing wax instead.
Iron and copper rods found with the ancient cells may have been used to series-connect
them for higher voltages.
Applications
Gold wasn't the only thing these pre-A.D. smiths used the cells for. They were
also able to plate silver and antimony. This, of course, speaks well for their knowledge
of chemistry, too. Some of the plating solutions they had to compound included ferrocyanides,
lye solutions and orate baths (gold dissolved in hydroxide). These chemicals were
available to the ancients, and they could have used any of them. The asphaltum that
sealed the batteries was the same material that Noah used to caulk the ark. The
Bible calls this material "bitumen" and it must have been an all-around sealing
compound, with numerous applications.
Other Finds
While the Parthians had only a limited knowledge of the electro-chemical batteries,
archaeologists have found the remains of four more in a magician's hut in the excavation
of Seleucia, a town not far from Khujut Rabu'a. The Berlin Museum had pieces of
ten more such batteries, possibly without realizing what they were.
Although Cleopatra didn't actually have electric lights in her palace, it is
entirely possible that Mark Antony presented her with gifts that he had picked up
in his travels, and that these gifts were electroplated. Surely, some of these electroplated
jewelry items must have found their way out of the Mesopotamian region and into
neighboring kingdoms.
While we are all doubtless impressed by our own technological achievements, it
gives one pause to think that one of our commonplace "modern" discoveries is not
a discovery at all, but a re-discovery of an ancient artifact! Who can surmise what
other secrets the ancients hold in shrouded mystery?
It is unfortunate that the knowledge and technology of the ancients was destroyed
before it could be recorded and saved, but each year more wonders of the old sciences
come to light. Who knows? Perhaps some day our own technology will catch up to theirs.
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